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Volume 67 | Issue 6 | Year 2019 | Article Id. IJETT-V67I6P210 | DOI : https://doi.org/10.14445/22315381/IJETT-V67I6P210
Effect of Amorphous Layer on the Microstructure and Properties of AlB4C Layered Composite
Paulo A. Inacio,Yubo Zhang ,Jinchuan.Jie, Tingju. Li
Citation :
Paulo A. Inacio,Yubo Zhang ,Jinchuan.Jie, Tingju. Li, "Effect of Amorphous Layer on the Microstructure and Properties of AlB4C Layered Composite," International Journal of Engineering Trends and Technology (IJETT), vol. 67, no. 6, pp. 52-58, 2019. Crossref, https://doi.org/10.14445/22315381/IJETT-V67I6P210
Abstract
An Al-Al+B4C-Al layered composite was produced by semi-continuous casting and hot rolling method, the innerlayer is Almatrix reinforced by 40wt.% B4C (F60), while the outlayer is pure Al. The result shows that the composite innerlayer (Al-B4C) has a high macrohardness of 43HBS1.5/125/30, once the outlayer pure Al has 16.5HBS1.5/125/30. However, due to the significant difference between Al and B4C in the inner layer, there are always defects near their interface and there is a sharp hardness gradient. By means of surface alloying, oxidation and acid attack on the reinforcement surface, a microamorphous transition (MAT) layer was found bounding the reinforcement’s particles. The microhardness behaviour shows the MATlayer has ~900HV (1Kgf/15s) on the reinforcement boundary and decays exponentially until the transition layer have no effect on the Almatrix (~32HV). This MAT layer bounding the reinforcement reduces the properties gradient and raises the composability, leading to a better impact resistance
Keywords
B4C, layered composite, Amorphous Layer, Reinforcementtreatment
References
[1] G. Y. Xu, Y. H. Yu, Y. B. Zhang, T. J Li, T. M. Wang. “Effect of B4C particle size on the mechanical properties of B4C reinforced aluminum matrix layered composite”. SECM, v. 26, Issue 1, p. 53-61.
[2] Y.Z. Li, Q.Z. Wang, W.G. Wang, B.L. Xiao, Z.Y. Ma, “Effect of interfacial reaction on age-hardening ability of B4C/6061Al composites”, Materials Science and Engineering A 620, pp. 445-453.
[3] Vikrant Chandel, Onkar Singh Bhatia "Fabrication and Characterization of Al 7075-Cenosphere Composite & its comparison with pure Al 7075", International Journal of Engineering Trends and Technology (IJETT), V29(3), pp. 133-142 Nov. 2015.
[4] Y. B. Zhang, Y. H. Yu, G. Y. Xu, Y. Fu, T. J. Li, T. G. Wang, Q. T. Guo, “Microstructure and Performance of a Three-Layered Al/7075–B4C/Al Composite Prepared by Semi Continuous Casting and Hot Rolling”,Metallurgy Journal 8(8):600. 2017.
[5] F. Thévenot. “Boron Carbide A Comprehensive Review”. J. Eur. Ceram. Soc 6, pp. 205-225, 1990.
[6] N. K. Shrestha, M. Kawai, T.Saji. “Co-deposition of B4C particles and nickel under the influence of a redox-active surfactant and anti-wear property of the coatings”. Surface & Coatings Tech. pp.2414-2419, 2005.
[7] A. Ektarawong, S.I. Simak, L Hultman, J. Birch,B. Alling. “First-principles study of configurational disorder in B4C using a superatom-special quasirandom structure method”.Physical Review B, Vol. 90, Issue 2, July. 2014.
[8] J. H. Wang, Y. He, Z. F. Xie, C. L. Chen, Q. B. Yang, C.L Zhang, B. Y. Wang, Y. Q. Zhan, T. H. Zhao, “Functionalized boron carbide for enhancement of anticorrosion performance of epoxy resin”, Polymers Adv. Technologies, pp. 758-766, Feb. 2018.
[9] I. Topcua, H.O. Gulsoyb, N. Kadiogluc, A.N. Gulluoglua. “Processing and mechanical properties of B4C reinforced Al matrix composites”. Journal of Alloys and Compounds, 482,pp. 516-521, 2009.
[10] R. Telle. “Oxidation behavior of B4C-SiC composites with various microstructures”. AIP Conference Proceedings, 1991, 231, p. 553.
[11] L. M. Litz, R. A. Mercuri. “Oxidation of Boron Carbide by Air, Water, and Air-Water Mixtures at Elevated Temperatures”.Journal of The Electrochemical Society 110(8), Jan. 1963.
[12] D. M. Bylander, L. Kleinman, S. B. Lee. Self-consistent calculations of the energy bands and bonding properties of B12C3. Phys. Rev. B42, 1990.
[13] E. Ghasali, M. Alizadeh, T. Ebadzadeh, A.H. Pakseresht, A. Rahbari. Investigation on microstructural and mechanical properties of B4C-aluminum matrix composites prepared by microwave sintering. J Mater Res Technol;4(4), p. 411-415, 2015.
[14] H.Courtney, Thomas. Mechanical behavior of materials.2nd ed,Boston: McGraw Hill. 2000.
[15] D. M. Scruggs, “Composite material bonded by an amorphous metal, and preparation thereof”,United States patent,US4621031A, August, 01,1994.
[16] L. F. Bailey, R. J. Bennett, “DICOR® Surface Treatments for Enhanced Bonding?Journal of Dental Research 67(6), p. 925-3, Jul, 1988.
[17] V. A. Lavrenko, A. P. Pomytkin, P. S. Kislyj, B. L. Grabchuk, “Kinetics of High-Temperature Oxidationof Boron Carbide in Oxygen”, Oxidation of Metals, Vol. 10, No. 2, 1976.
[18] C.W. San Marchi. “Processing of Aluminum-Nickel Amorphous by Reactive Infiltration”, PHD Eng. thesis,MIT, USA, 1997.
[19] (2018) AZoN, Scientists Develop Nickel Aluminide Composite Material that Can Cut Through Cast Iron and Granite, [Online]. Available: https://www.azom.com/news.aspx?newsID=3866
[20] B. K. Ozcelik, C. Ergun, “Effect of Ni on The Synthesize Boron Carbide Via Aerosol Method”, Researchgate.RG.2.1.4392.1765, July 2015.
[21] H. Shmue. “Reaction-bonded boron carbide for lightweight armor: The interrelationship between processing, microstructure, and mechanical properties”,American Ceramic Society Bulletin, Vol. 96, No. 6 pp. 20-26, August 2007.
[22] A. Kilicarslan, F. Toptan, I. Kerti, S. Piskin, “Oxidation of boron carbide particles at low temperatures”,Mat. Letters, 128(1), pp. 224-226, 2014.
[23] Y.Q. Li, T. Qiu, “Oxidation behaviour of boron carbide powder”, Materials Science and EngineeringA 444, pp. 184-191, 2007.
[24] (2018) NIH U.S. Compound Summary for CID 24638. Chlorosulfonic acid. [Online] available : https://pubchem.ncbi.nlm.nih.gov/compound/Chlorosulfuric_acid#section=Top.
[25] Redankamma Yenumula, Srinivasulu Dorasila, CV Ramana Murthy Naidu S, Rambabu Kalpukuri, "Experimental Investigation of Mechanical Properties of Pure Al-Sic Metal Matrix Composite by Stir Casting Method", International Journal of Engineering Trends and Technology (IJETT), V59(3),148-154 May 2018.
[26] M. Kern, Vol. P. Thompson, “Bonding to glass infiltrated alumina ceramic: Adhesive methods and their durability”?The Journal of Prosthetic Dentistry,73(3):240-9, Mar, 2005.
[27] Y. Chaiyabutr, S. Mcgowan, K. M. Phillips, J. C. Kois, R. A. Giordano, “The effect of hydrofluoric acid surface treatment and bond strength of a zirconia veneering ceramic”, The Journal of Prosthetic Dentistry Vol. 100, Issue 3, Sept. 2008, p. 194-202.
[28] Mike Glazer, International Tables for Crystallography. International Union of Crystallography, Vol. A, ch. 2.3, pp. 193-687, 2006.
[29] J. A. Bigdeloo, And A. M. Hadian, “Synthesis of High Purity Micron Size Boron Carbide Powder from B2O3/C Precursor”, International Journal of Recent Trends in Engineering, Vol. 1, No. 5, May 2009.
[30] I.A. Rakhmatullin, A.A. Sivkov, A.F. Makarova, “Boron carbide nanopowder synthesized using electrical discharge plasma”, Journal of Physics, Conference Series 552, 012008, 2014.
[31] H. Saitoh, K. Yoshida, W. A. Yarbrougha. “Crystal structure of new composition boron-rich boron nitride using Raman spectroscopy”. J. Mater. Res., Vol. 8, No. 1, Jan 1993.
[32] D. R. Tallant, T. L. Aselage, A. N. Campbell, and D. Emin.“Boron carbide structure by Raman spectroscopy”,Phys. Rev. B 40, p. 5649, 1989.
[33] D. R. Tallant, T. L. Aselage, and D. Emin, “Structure of icosahedral borides by Raman spectroscopy”, AIP Conference Proceedings231, p. 301, 1991.
[34] K. I. Sasaki, Y. Tokura , T. Sogawa.“The Origin of Raman D Band: Bonding and Antibonding Orbitals in Graphene”, Crystals, Vol. 3, pp. 120-140, 2013.
[35] F. Davar, Z. Fereshteh, M. Salavati-Niasari, “Nanoparticles Ni and NiO: Synthesis, characterization and magnetic properties”, Journal of Alloys and Compounds 476, pp. 797-801, 2009.
[36] B. Raj, K. Bhanu, S. Rao,Mechanical Testing: Overview, Encyclopedia of Materials: Science and Technology, 2001.
[37] F. Ouchterlony,Fracture Toughness Testing of Rock. Rossmanith, H.P. (eds) Rock Fracture Mechanics. International Centre for Mechanical Sciences, Vol. 275, Springer, Vienna, 1983.